Geochemistry
Sampling and analytical techniques
Eight representative samples were selected for geochemical analysis and the whole rock major element analyses for three samples (AG-2, AG-4, AG-6) were carried out at National Geophysical Research Institute (NGRI), Hyderabad, India on XRF and whole rock major and trace element analyses for five other samples (AG-8, AG-10, NK-12, NK-13, NK-18) were carried out at Regional Sophisticated Instrumentation Centre, IIT Bombay, Mumbai, India on XRF (Philips PW 2404). The rare earth elements (REE) for the samples (AG-2, AG-4, and AG-6) were carried out on ICP-MS (Perkin Elmer Sciex ELAN DRC II) at NGRI, Hyderabad. Two representative granulite samples S08-27 and S08-42 were analysed at (NGRI), Hyderabad, India for major trace and REE. The accuracy (% RSD) for major oxides and trace elements is 1% and the precision is 0.5% for the data generated from IIT Bombay. The detection limit is 1ppm for most of the elements. The precision of ICP-MS data are <5% RSD for all the trace elements including the REE. Whole rock major and trace element data of the granitoids and the granulites are presented in Table 1.
Table 1. Whole rock geochemical analyses for the MHM Granitoids and the Shillong plateau basement granulites
Granitoids | Granulites | |||||||||
---|---|---|---|---|---|---|---|---|---|---|
Sample No | AG-2+ | AG-4+ | AG-6+ | AG-8+ | AG-10+ | NK-12+ | NK-13+ | NK-18+ | S08-27* | S08-42* |
SiO2 | 72.36 | 70.65 | 73.3 | 64.54 | 64.67 | 73.8 | 75.79 | 73.38 | 76.7 | 74.73 |
TiO2 | 0.39 | 0.52 | 0.47 | 1.14 | 1.23 | 0.35 | 0.15 | 0.34 | 0.19 | 0.25 |
Al2O3 | 13.04 | 13.32 | 12.58 | 13.66 | 13.95 | 13.52 | 13 | 13.44 | 12.99 | 13.25 |
Fe2O3* | 2.64 | 3.53 | 2.48 | 5.87 | 5.8 | 1.97 | 0.65 | 2.24 | 0.84 | 1 |
MnO | 0.04 | 0.01 | 0.08 | 0.12 | 0.12 | 0.1 | 0.05 | 0.1 | 0.01 | 0.01 |
MgO | 0.95 | 1.21 | 1.09 | 2.99 | 2.82 | 1.09 | 0.62 | 1.06 | 0.08 | 0.44 |
CaO | 1.62 | 1.93 | 1.86 | 3.3 | 3.09 | 1.32 | 1.26 | 1.38 | 0.7 | 0.36 |
Na2O | 2.17 | 2.17 | 2.04 | 1.85 | 2.12 | 2.33 | 2 | 2.24 | 3.83 | 2.89 |
K2O | 5.92 | 5.79 | 5.2 | 5.65 | 5.38 | 5.1 | 5.52 | 4.93 | 3.4 | 5.37 |
P2O5 | 0.08 | 0.13 | 0.12 | 0.42 | 0.39 | 0.12 | 0.08 | 0.09 | 0.01 | 0.02 |
Total | 98.21 | 99.26 | 99.22 | 99.54 | 99.57 | 99.7 | 99.12 | 99.2 | 98.74 | 98.34 |
Rb | 41 | 37 | 38 | 17 | 18 | 51 | 34 | 43 | 69 | 157 |
Th | 44 | 39 | 46 | 5 | 5 | 27 | 13 | 33 | 35 | 18 |
U | 42 | 35 | 35 | 30 | 34 | 35 | 29 | 34 | 4 | 1 |
Nb | 7 | 13 | 16 | 8 | 4 | 12 | 3 | 11 | 3 | 2 |
Sr | 55 | 66 | 68 | 125 | 115 | 51 | 28 | 59 | 55 | 59 |
Zr | 93 | 120 | 114 | 173 | 154 | 82 | 41 | 79 | 102 | 66 |
Y | 22 | 24 | 26 | 13 | 9 | 25 | 13 | 28 | 15 | 5 |
La | 139.58 | 233.26 | 219.99 | nd | nd | nd | nd | nd | 90.85 | 30.15 |
Ce | 267.76 | 440.65 | 416.21 | nd | nd | nd | nd | nd | 242.79 | 50.45 |
Pr | 26.61 | 43.41 | 41.72 | nd | nd | nd | nd | nd | 28.96 | 4.47 |
Nd | 91.96 | 148.51 | 144.99 | nd | nd | nd | nd | nd | 111.43 | 15.06 |
Sm | 14.34 | 22.65 | 23.02 | nd | nd | nd | nd | nd | 19.45 | 2.22 |
Eu | 1.39 | 1.93 | 2.05 | nd | nd | nd | nd | nd | 1.2 | 0.67 |
Gd | 10.91 | 18.16 | 18.153 | nd | nd | nd | nd | nd | 14.07 | 2 |
Tb | 1.38 | 2.3 | 2.44 | nd | nd | nd | nd | nd | 1.62 | 0.23 |
Dy | 7.41 | 12.38 | 13.8 | nd | nd | nd | nd | nd | 5.52 | 1.1 |
Ho | 0.75 | 1.33 | 1.48 | nd | nd | nd | nd | nd | 0.35 | 0.1 |
Er | 2.64 | 4.74 | 5.53 | nd | nd | nd | nd | nd | 1.05 | 0.34 |
Tm | 0.33 | 0.6 | 0.75 | nd | nd | nd | nd | nd | 0.08 | 0.03 |
Yb | 3.37 | 5.85 | 7.72 | nd | nd | nd | nd | nd | 0.83 | 0.37 |
Lu | 0.52 | 0.92 | 1.28 | nd | nd | nd | nd | nd | 0.14 | 0.08 |